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Spontaneous transitions of an isolated system from one macroscopic state to another (relaxation processes) are accompanied by a change of entropy. Following Jaynes’ MaxEnt formalism it is shown that practically all the possible microscopic developments of a system, within a fixed time interval, are accompanied by the maximum possible entropy change. In other words relaxation processes are accompanied by maximum entropy production.
relaxation processes; MEP principle; MaxEnt formalism
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